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91.
Abdul Malek G. Ranga Rao Tiju Thomas 《International Journal of Hydrogen Energy》2021,46(52):26677-26692
Heavy metals (Hg, Cd, Pb, etc.) are micro-pollutants and result in water contamination. Significant bio-concentration of heavy metal like Hg can lead to fatal disease such as Minamata. Given this context, heavy metal removal from wastewater is essential before discharge. The wastewater treatment process requires considerable amount of energy which is being met by the conventional carbon-based fuels. This contributes to the global carbon dioxide emission, and hence global warming. Therefore, if clean energy sourcing is enabled during the treatment of the wastewater; it would offer obvious advantages. If the energy production is ‘clean’ and achieved via the process itself, it would serve two outcomes: (a) meeting the energy demand for wastewater treatment, and (b) getting rid of the need for external ‘carbon-based’ energy. Recently a few research articles have reported simultaneous clean energy production from wastewater during its treatment. Thus, the energy demand of the wastewater treatment process can be potentially met with the clean energy produced during the process. In this review, we will discuss mercury-contaminated wastewater treatment with simultaneous hydrogen production. We will provide a brief overview of waste-to-wealth approaches currently prevailing in water economy, recent mercury removal processes, and discuss future possibilities of self-sustained Hg-contaminated wastewater treatment. 相似文献
92.
Enrico Kleebusch Christian Patzig Thomas Höche Christian Rüssel 《Ceramics International》2018,44(16):19818-19824
Glass-ceramics based on lithium-alumo-silicate glasses are commercially important for a wide range of applications, due to their special properties, like a vanishing thermal expansion. In order to tailor these properties, the composition of the glass and the temperature/time schedule are crucial factors. For the industrial production of most lithium-alumo-silicate glasses, high melting temperatures are required due to the high viscosities of the respective melt compositions. In this study, a simplified lithium-alumo-silicate glass composition with ZrO2 as nucleating agent, on the basis of the commercially available Robax® composition, is studied. Adding boron oxide leads to lower viscosities of the glass melt and notably lower melting temperatures may be supplied. The resulting glass is investigated using X-ray diffraction and transmission electron microscopy. During the crystallization process, phases such as ZrO2 and β-quartz types are formed. The microstructure of the glass ceramics is notably coarser than that of glass-ceramics which are obtained from lithium-alumo-silicate glasses of standard compositions. EDX-analyses indicate a considerable enrichment of chemical elements in comparatively small areas of the microstructure. Especially boron oxide is found to be enriched in the residual glass of the investigated glass-ceramics. 相似文献
93.
A novel batch plant for supercritical CO2 applications is proposed which is not equipped with expensive components, such as high‐pressure pumps, making it particularly suitable for bench‐scale use. For the first time, the use of a hanging scale is suggested to weigh the amount of CO2 required for the experiment and the use of the thermodynamics to reach the working conditions. The rig is able to cover different applications, e.g., aerogel drying, impregnation, and extraction, showing high flexibility. An approximate cost analysis has been performed considering as a reference a 150‐mL vessel. It has been calculated that both the setup and running costs are considerably lower than the common batch and semicontinuous rigs. 相似文献
94.
95.
Matthias Ahlhelm David Werner Johanna Maier Johannes Abel Thomas Behnisch Tassilo Moritz Alexander Michaelis Maik Gude 《Journal of the European Ceramic Society》2018,38(9):3369-3378
The so-called Freeze Foaming method aims at manufacturing ceramic cellular scaffolds for diverse applications. One application is dedicated to potential bone replacement material featuring open, micro and interconnected porosity. However, the main challenges of this foaming method is to achieve a homogeneous pore morphology. In a current project, the authors throw light on the bubble/pore and strut formation of this process by in situ computed tomography. This allows for evaluating varying process parameter’s effects on the growth of the ceramic foam during the foaming process. As first result and basis for CT analysis, a stable and reproducible model suspension was developed which resulted in reproducible foam structures. In dependence of selected process parameters like pressure reduction rate or air content in the ceramic suspension resulting Freeze Foams became adjustable with regard to their pore morphology. Pore size and distribution data as well as the porosity were characterized and evaluated accordingly. 相似文献
96.
Harry Charalambous Shikhar Krishn Jha Kent Harrison Christian Ryan Thomas Lay Thomas Tsakalakos 《Journal of the European Ceramic Society》2018,38(10):3689-3693
In conventional flash sintering, the current rises nonlinearly to a set current limit, accompanied by a spike in the power density. This sudden power spike may cause hot spot formation, in which current preferentially channels through a small area, causing localized melting while other areas remain unsintered. By using a controlled current ramp early on the sudden power spike can be avoided. In addition, by changing the ramp rate material properties such as porosity, grain size and conductivity can be tuned. 相似文献
97.
Thomas Schulz Timmy Reimann Arne Bochmann Andre Vogel Beate Capraro Björn Mieller Steffen Teichert Jörg Töpfer 《Journal of the European Ceramic Society》2018,38(4):1600-1607
The sintering behavior and the thermoelectric performance of Ca3Co4O9 multilayer laminates were studied, and a multilayer thermoelectric generator was fabricated. Compacts and multilayer samples with anisotropic microstructure and residual porosity were obtained after conventional sintering at 920 °C, whereas dense and isotropic multilayer samples were prepared by firing at 1200 °C and reoxidation at 900 °C. A hot-pressed sample has a dense and anisotropic microstructure. Samples sintered at 920 °C exhibit low electrical conductivity due to the low density, whereas the Seebeck coefficient is not sensitive to preparation conditions. However, thermal conductivity of multilayers is very low, and, hence acceptable ZT values are obtained. A transversal multilayer thermoelectric generator (TMLTEG) was fabricated by stacking layers of Ca3Co4O9 green tapes, AgPd conductor printing, and co-firing at 920 °C. The TMLTEG has a power output of 3 mW at ΔT = 200 K in the temperature interval of 25 °C to 300 °C. 相似文献
98.
Post‐polymerization modification of bio‐based polymers: maximizing the high functionality of polymers derived from biomass 下载免费PDF全文
Thomas J Farmer James W Comerford Alessandro Pellis Tobias Robert 《Polymer International》2018,67(7):775-789
The renaissance of the bio‐based chemical industry over the last 20 years has seen an ever growing interest in the synthesis of new bio‐based polymers. The building blocks of these new polymers, so called platform molecules, contain significantly more chemical functionality than their petrochemical counterparts (such as ethene, propene and para‐xylene). As a result bio‐based polymers often contain greater residual chemical functionality in their chains, with groups such as alkenes and hydroxyls commonly observed. These functional groups can act as sites for post‐polymerization modification (PPM), thus further extending the range of applications for bio‐based polymers by tailoring the polymers' final properties. This mini‐review highlights some of the most recent and compelling examples of how to make use of bio‐based polymers with residual functional groups for PPM. It also looks at how the emerging interdisciplinary field of enzymatic polymer synthesis allows for increased functionality in polymers by avoiding side‐reactions as a result of milder reaction conditions, and additionally offers an alternative means of polymer surface modification. © 2018 Society of Chemical Industry 相似文献
99.
Bernhard Atorf Simon Friesen Roman Rennerich Holger Mühlenbernd Thomas Zentgraf Heinz Kitzerow 《Polymer Science Series C》2018,60(1):55-62
A switchable metasurface composed of plasmonic split ring resonators and a polymer-stabilized liquid crystal blue phase is developed. Owing to field-induced birefringence (electro-optic Kerr effect), the state of polarization of the incident near infrared radiation changes, when a voltage is applied to the liquid crystal. Thus, different resonant modes of the split ring resonators can be addressed and the transmission spectrum changes accordingly. In comparison with other liquid crystal phases, blue phases have several advantages. For example, they are optically isotropic in the field-off state, so that no alignment layer is required. The results of the present study indicate that the advantages of these mesophases can be utilized for switchable metasurfaces. 相似文献
100.
Landsiedel Justus Root Waleri Schramm Christian Menzel Alexander Witzleben Steffen Bechtold Thomas Pham Tung 《Nano Research》2020,13(10):2658-2664
Nano Research - Development of colored surfaces by formation of nano-structured aggregates is a widely used strategy in nature to color lightweight structures (e.g. butterflies) without the use of... 相似文献